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Photochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesis
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4873575Photochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesishttps://www.gandhi.com.mx/photochemical-and-electrochemical-activation-strategies-of-c-sp3--based-building-blocks-for-organic-synthesis-9789819989942/phttps://gandhi.vtexassets.com/arquivos/ids/4432372/image.jpg?v=63847593250803000027323036MXNSpringer Nature SingaporeInStock/Ebooks/<p>This book addresses novel C(sp3)-C(sp2) and C(sp3)-heteroatom bond-forming reactions. Two strategies are given in the book using photoredox or electrochemical methods. The first strategy describes that the hydroalkylation of alkynes via photoredox-mediated Ni/Ir dual catalysis produces trisubstituted alkenes as versatile synthetic building blocks for the synthesis of pharmaceutical agents and natural products. High regioselectivity and E/Z-selectivity were achieved by introducing silyl groups that can provide steric and electronic effects to these selectivities with extensive opportunities for post-functionalization.</p><p>The second strategy enables the development of C(sp3)-heteroatom bond-forming reactions through the electrochemical activation of C(sp3)-B bonds. The bonding of heteroatoms to carbon atoms has been an enduring subject of investigation for organic chemists. The function of most molecules is mainly determined by heteroatoms attached to the carbon atom, althoughthe backbone structure of organic compounds comprises carbon fragments.</p>...4622094Photochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesis27323036https://www.gandhi.com.mx/photochemical-and-electrochemical-activation-strategies-of-c-sp3--based-building-blocks-for-organic-synthesis-9789819989942/phttps://gandhi.vtexassets.com/arquivos/ids/4432372/image.jpg?v=638475932508030000InStockMXN99999DIEbook20249789819989942_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_<p>This book addresses novel C(sp3)-C(sp2) and C(sp3)-heteroatom bond-forming reactions. Two strategies are given in the book using photoredox or electrochemical methods. The first strategy describes that the hydroalkylation of alkynes via photoredox-mediated Ni/Ir dual catalysis produces trisubstituted alkenes as versatile synthetic building blocks for the synthesis of pharmaceutical agents and natural products. High regioselectivity and E/Z-selectivity were achieved by introducing silyl groups that can provide steric and electronic effects to these selectivities with extensive opportunities for post-functionalization.</p><p>The second strategy enables the development of C(sp3)-heteroatom bond-forming reactions through the electrochemical activation of C(sp3)-B bonds. The bonding of heteroatoms to carbon atoms has been an enduring subject of investigation for organic chemists. The function of most molecules is mainly determined by heteroatoms attached to the carbon atom, althoughthe backbone structure of organic compounds comprises carbon fragments.</p>...9789819989942_Springer Nature Singaporelibro_electonico_9789819989942_9789819989942Su YongInglésMéxico2024-03-28T00:00:00+00:00Springer Nature Singapore